Gather and measure all ingredients, including juicing and zesting the lemons.
Place chicken breasts at the bottom of the slow cooker. Pour in chicken broth and add lemon juice, lemon zest, olive oil, oregano, thyme, garlic, salt, and pepper. Mix gently.
Cover and cook on LOW for 6 to 7 hours or on HIGH for 3 to 4 hours.
About 30 minutes before serving, cook the rice by bringing water to a boil and adding rice. Simmer for 18 to 20 minutes.
Once chicken is cooked, shred it in the slow cooker and mix it back into the sauce.
Serve over fluffy rice and garnish with fresh parsley.
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Notes
Store leftovers in an airtight container in the refrigerator for up to 3-4 days.